The strength of a covalent bond depends on the extent of overlap of the orbitals involved. The mutual attraction between this negatively charged electron pair and the two atoms’ positively charged nuclei contributes to the link between the two atoms that we define as a covalent bond. According to valence bond theory, a covalent bond results when two conditions are met: (1) an orbital on one atom overlaps an orbital on a second atom and (2) the single electrons in each orbital combine to form an electron pair. We say that orbitals on two different atoms overlap when a portion of one orbital and a portion of a second orbital occupy the same region of space. Valence bond theory describes a covalent bond as the overlap of singly-occupied atomic orbitals that yield a pair of electrons shared between the two bonded atoms. Furthermore, VSEPR does not provide an explanation of chemical bonding. The VSEPR model, however, does not accurately predict all molecular shapes or electron domain geometries. For example, the VSEPR model has gained widespread acceptance because of its simplicity and its ability to predict the three-dimensional molecular shapes of many molecules that are consistent with experimental data. For a theory to be accepted, it must explain experimental data and be able to predict behavior. | Key Concepts and Summary | Glossary | End of Section Exercises | Valence Bond TheoryĪs we know, a scientific theory is a strongly supported explanation for observed natural laws or large bodies of experimental data. | Valence Bond Theory | sp Hybridization | sp 2 Hybridization | sp 3 Hybridization | Assigning Hybrid Orbitals to Central Atoms | Apply valence bond theory to predict orbital hybridization in atoms.
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More reverie than textbook, Raven Kaldera’s work makes for an enticing read.”» Kaldera brings a great sense of storytelling to his explanations of the moon’s place in our lives.”» Besides simply understanding the celestial path the moon takes, Kaldera shows the reader how the moon is a metaphor for our own lives, our personal relationships, and our general disposition towards the world. Kaldera walks with the reader across the varied path of the moon as it glides through all of its 96 incarnations. «“This thick tome is a complete introduction to developing and understanding a personal relationship to the phases of the moon. Easy-to-understand astrology for beginners and beyond.”» Beginners will finish with an understanding of how to find their moon sign and phase through an astrological chart, and more advanced readers with a greater interest in using the moon as a life guide will find much useful information here. The heart of the book tells the stories of 96 moon phases and moon-sign combinations, from the Infant's Moon to the Prophet's moon. «“Astrology can be overwhelming for novices, but this guide makes for both easy reading and comprehension. This book is an exceptional tool for keeping ourselves on an even keel during these challenging times.”»ĭonna Cunningham, MSW, author of Moon Signs and The Moon in Your Life By understanding the current Moon phase and the phase we were born under, we can more easily manage our responses to the ebb and flow of both stressful and joyful intervals. «“Raven Kaldera’s Moon Phase Astrology is a much-needed addition to astrology’s literature on the Moon and how it affects our emotional and spiritual approach to life. Susan Selene, internationally known psychic and astrologer The wisdom of the ages permeates this methodical collection of information, enticing you to learn more about your dance through the seasons and cycles of the Moon based on the lunar phase at the time of birth. «“In Moon Phase Astrology, Raven Kaldera weaves a magical tale of Moon lore, astrology, archetypes, and practical spiritual insight that imparts deep knowledge and understanding of the Moon’s impact on our lives. Including evocative quotes illuminating the nature of each Moon, Kaldera shows how to use your natal Moon's astrological sign and phase to find your "hidden Moons"-the shadows cast by passing Moons-and predict how current and approaching Moons will affect you. Exploring the influences each Moon archetype has on us as it passes, the author reveals which Moons are the most difficult, what innate qualities each Moon brings out in us, and what we can do to honor each Moon. Telling the stories of the heart of all 96 Moon phase and Moon sign combinations, Raven Kaldera explains the creative gifts and emotional challenges bestowed upon those born under each Moon archetype as well as how to nurture the positive traits and improve-or at least discourage-the negative ones. Through its 8 phases and its wandering dance through each of the 12 signs of the Zodiac-from the Infant's Moon (the New Moon in Aries) to the Storyteller's Moon (the Full Moon in Gemini) to the Prophet's Moon (the waning Balsamic Moon in Aquarius)-the Moon shares its story in 96 different ways. The Moon's ever-changing phases offer a way to deepen our understanding of our natal Moon sign as well as the Moon's day-to-day influence on our emotional tides. THE LENDER MAY BE SUBJECT TO FEDERAL LENDING LAWS. THE LENDER MAY NOT BE SUBJECT TO ALL VERMONT LENDING LAWS. INFORMATION RECEIVED WILL BE SHARED WITH ONE OR MORE THIRD PARTIES IN CONNECTION WITH YOUR LOAN INQUIRY. It is very important to do your own analysis before making any investment based on your own personal circumstances and consult with your own investment, financial, tax and legal advisers.Ĭompany NMLS Consumer Access #2110672 MORTGAGE BROKER ONLY, NOT A MORTGAGE LENDER OR MORTGAGE CORRESPONDENT LENDER Our content is intended to be used for general information purposes only. Companies displayed may pay us to be Authorized or when you click a link, call a number or fill a form on our site. $8,453 flat rate for new conventional system (3-bedroom house)ĬonsumerAffairs is not a government agency. $5,255 for repiping 1,500 sf of home with PEX To help you get an idea of prices to expect, we created this table showing the average cost of typical plumbing services in Chicago: Type of Serviceįaucets, pipes and fixtures installation or repair The estimated fixed-rate cost includes material to be used, labor cost, distance traveled, time frame and discounts, rebates and other special offers. Several factors affect the cost of plumbing in Chicago including the type and complexity of the problem, the location of the job, the weather condition, if it's an emergency or non-emergency situation and relevant laws in the city. They're also a great way to be aware of limited deals and temporary coupons. Print ads: Print ads in your local Chicago dailies are helpful because they focus on news and information in and around your community.Facebook, Twitter and other social media platforms are also useful for a more extensive word of mouth. These companies do their own internal vetting of professionals before they list them on their pages. Referral sites: Sites like ConsumerAffairs are great sources to consider.You may also have friends in real estate or construction who would surely know a good one because they have parallel businesses. Ask your family or coworkers who have had plumbing work done and were happy with the result.
“When you’re a Black, femme-presenting person in modern society, you get told you can’t be a lot of things: You can’t be emotional. You are more treasured than the greenest emerald. Your tears are the water that fills the rivers of the earthĭo not listen when they tell you not to speakĭo not listen when they attempt to strip away your protection “Second of all, her writing was just exquisite and her commitment level was really mature for a ninth grader.”ĭo not listen when they tell you not to cry “First of all, I can never forget her name,” said Mayson, who is on the Free Library of Philadelphia’s poet laureate selection committee. As a freshman, she took a class with the city’s former poet laureate, Trapeta Mayson, who teaches a poetry workshop at Cristo Rey as an artist in residence.Įven though the class was three years ago and held virtually due to the pandemic, Oyeniyi stood out to Mayson. I want us to be more in tune with our communities and not be so quick to judge.”īorn in New York of Liberian and Nigerian descent, Oyeniyi grew up in Philadelphia where she is now a senior at Cristo Rey High School in North Philadelphia. We’re gonna help each other get out of it. This homelessness epidemic does not define us. “Every time I walk outside or go on the news it’s, like, gun violence, and there’s homeless people all over who are not given common dignity,” said Oyeniyi, 17, who lives in the Lawncrest neighborhood. Oyewumi Oyeniyi is Philadelphia’s new Youth Poet Laureate. WHYY thanks our sponsors - become a WHYY sponsor But as tensions rise, Acadia is under pressure from both factions to take a side and help eradicate the other. The leader of Acadia, a synth named DiMA, provides the townspeople with the fog condensers while giving the Children of Atom their own base, a former submarine named The Nucleus for them to live in. Stuck between the two sides is Acadia, which only wants peace and harmony. The reason for the tension is the radiated fog that has been slowly overcoming the island the people of Far Harbor cannot live with the fog and they use machines called fog condensers to create fresh air, an act viewed as sacrilege by the Children of Atom who worship radiation and consider the fog the will of Atom to make the whole island a holy place. Traveling to Far Harbor, the Sole Survivor learns that on the island, there are three factions that have been locked in dispute with each other Far Harbor's citizens, the Church of the Children of Atom, and Acadia, a place specially set up as a synth refuge. A brief investigation at the Nakano residence will tell the player that Kasumi believes herself to be a synth replacement, and that she's decided to leave her parents and travel to a place far north called Far Harbor to be with people like her. Arriving at the office, Ellie Perkins will tell Nick and the Sole Survivor to investigate the case of Kasumi Nakano - the missing daughter of a fisherman living beyond the northeast boundaries of the Commonwealth. The add-on starts off with the quest Far From Home when the player character listens to a radio message from the Valentine Detective Agency after completing the quest Getting a Clue, or when the player goes to the Nakano residence (possibly even before meeting Nick Valentine). This leads to the fighting between the Far Harbor citizens and the Children of Atom, but a greater plot involves a synth, who has ties with Nick Valentine. There, the Sole Survivor will search for a young woman, Kasumi Nakano, and a colony of synths. Additionally, I have facilitated the online registration process (organizing and implementing all website and online form building) for corporate trade-shows and trade tasting events involving several hundred exhibitors.The add-on is set on Mount Desert Island, off the coast of Maine. My responsibilities included cocktail creation and beverage management, building experiential and memorable interactive showcases, as well as public relations and brand management. Walker included managing and coordinating the sponsorship of our spirit brands at many intimate and large scale events across Massachusetts. Part of my Product Marketing Manager role at M.S. Beginning in the 1990s, I produced and curated a weekly film series at non-traditional micro-venues (galleries, bars, art-house cinemas) throughout Boston, Providence and Portland, Maine to rave critical reviews.ĭuring my ten years at The Video Underground, I ran seasonal outdoor screenings that showcased filmmakers from around the world to loyal audiences and leveraged long-term sponsorships from local brands (such as Harpoon Brewery) which provided broad support and cross-promotion opportunities. I have been managing, curating and producing events in multiple industries for over two decades. Keep connected to our site to get more wiki on her. She is a social magnet who is followed by thousands of people. If you are a fan, don't forget to connect to her via social networking sites like Twitter (41.9 k followers) and Instagram (above 60k followers). The role also won her 2013's Young Artist Award in the category Best Performance in a Feature Film - Leading Young Actress. In the American divorce saga she plays the role of Louise Brooks, an audacious girl/ straight A-student and young environmentalist who along with her siblings are witnessing aftermath of their parents' divorce.Īnd, the role of Alex in Paranormal Activity 4 showed us that she can lead a movie anytime if a right role flies in. Her long-running role till date Louise Brooks in Gary Unmarried. In fact, her decision this year to take a year off from her studies to focus on her acting career proved that she is an astute teen.Īnyway, until verifiable sources say otherwise, it will be safe to say that she is a single teen with no boyfriend history.īorn on February 8, 1997, in United States to a happy family consisting of supporting parents namely father David Newton and mother Danny Newton, American teen actress Kathryn Newton is best known for her roles in television series including All My Children (2001-2004), Garry Unmarried (2008-2010), Dog With a Blog (2013-2014) and Supernatural (2014-present), and in movies namely Paranormal Activity 4 and Bad Teacher. Besides, she has just graduated this year (in June from Notre Dame High School in Southern California and helped the school golf team to win three championship) and that means she will have more time to invest in herself and her love life. That doesn't mean she can’t have a boyfriend. Well, she is just 18 and already extremely busy balancing her acting career, golfing interest and personal life. Similarly, we couldn’t find a single bikini picture of the blonde teen (worth a wait).Īnyway, the big question you all wanted to be answered. Unfortunately, her net worth is not known. Her other prominent hobby include collecting shoes. What's sexy about her is her roles will leave you in the state of wanting more, as she is an actress with loads of potentialities, an interesting hobby and multi-dimensional personality. However, she has got a high physical sex appeal, thanks to her hot slender body with toned legs, shapely breasts, winsome face and well-maintained blonde hair. Now moving on to her body configuration, she is not a tall woman with the height of 5 feet and 4 inches. Nevertheless, she is speedily progressing in the show-biz industry, yet she dreams of being a professional golfer. Plus, she is severely hot (she is a chic), yet she is really sweet and down-to-earth. She describes herself as a geek, yet she is an achieved golfer. The Serbian tennis champion is ready fot he last tournaments of the season, with a clear goal: to remain world no.1.Officially started acting at the age of 4, American teen actress Kathyrn Newton is a complete package. This is one of the best sensations I've ever felt in sport." They told me about the Ryder Cup, but I didn't expect it to be like this. Nole made some statements regarding his experience during an interview with Sky Sport: "The atmosphere is magical. Ryder Cup, Novak Djokovic: "Magical atmosphere"ĭjokovic was paired with Noppert facing the team made up of Sainz and Perrino, demonstrating a certain quality in this sport too and his attitude to never lose one of the characteristics that made him great and able to conquer the numerous records that he boasts. While Pavin's team fielded the Ferrari player Sainz, the 2004 Golden Ball winner and winner of a Champions League with the Milan shirt Andriy Shevchenko, the actress Kathryn Newton, Tommaso Perrino currently number 6 in the world in the paralympic world golf ranking and former American football player Victor Cruz. The first featured the Serbian champion, Gareth Bale, the world number 1 Paralympic athlete Kipp Popert, the Italian Leonardo Fioravanti and the American YouTuber Garrett Hilbertt. No matter how we make it, ice cream is always a sweet, creamy, delicious summer treat! How do you make Mint Chocolate Chip Ice Cream? Sometimes we make super easy no-churn ice creams, and sometimes we make batches in our electric ice cream maker. We are huge ice cream fans, so it goes without saying that we make a lot of ice cream, especially in the summer months. Unlike custard base, this ice cream mixture does not use any egg yolks, nor does it need to simmer or boil in a saucepan. There is nothing better than fresh homemade ice cream. This recipe is one of my favorites, as it really takes less than five minutes to prep and get it into the ice cream maker. Make this homemade ice cream recipe with natural flavors, and avoid all artificial flavors, guar gum, cellulose gum, and corn syrup. it was so fresh tasting and different.This creamy Mint Chocolate Chip Ice Cream is made easily with seven ingredients like cream, mint flavoring, and chopped chocolate in your ice cream maker. The cream was enough to dilute it, though, and once it had been churned, it looked pretty much white. They still exuded a very dark gray color once chopped up fine. I was worried about the grayish color, so I tried to choose mostly mint leaves that had not discolored yet at all and were bright green, and no stems. It is indeed like pot ice cream, but in a good way. It is highly unusual and very herbaceous/grassy tasting. Perhaps the reason some of us are getting less than beautiful color from this ice cream is that we are using organic eggs?! Organic eggs have very orange/yellow yolks, so that might be it? I really liked this recipe, but it isn't off the charts so just three forks. And yes, the best way to add the chocolate is to melt it and then slowly pour it into the freezer as it churns. Mint flavor was distinct and fresh tasting, but not overpowering. It wound up with a nice smooth texture and light green color. Also, muddled the mint in the sugar first, then heated that together with the milk and cream. 1.5 cups cream, 1.5 cups 2% milk to make it lighter. Great recipe, although I altered it a bit. Everyone agreed, it was delicious and refreshing. This time I added a can of coconut milk instead of cream and omitted the chocolate chips. I have made this recipe before (with half the amount of mint) and liked it. I substituted 3 cups of half&half, halved the amount of mint and used bittersweet chocolate with cocoa nibs. I add mini semi sweet chips when I scoop it out so the chocolate doesn't freeze. I use 3 C of half and half, 1 C of mint leaves, and 4 egg yolks in place of 2 eggs. It got rave reviews from a 2 year old and the old folks too. I also cut down on the butterfat using 1 1/2 cups of whole milk and the same of half and half. Loved this! I used half of the stated mint but I think next time I would use 1 1/2 cups. I boiled the mint with the cream AND milk and then strained the mint out before mixing in the egg and sugar to make the custard. My green color was beautiful but then again it was FRESH! I got it out of the garden and immediately used it. I used the full 2 cups packed mint but made sure not to get any stems or bruised leaves. Not sure why you guys got a grey tint to your ice cream. I will never make this again, it is the worst ice cream recipe I have ever tried hands down. I made this ice cream and it was terrible, the color was identical to spinach, there were chunks even after I sieved it twice, it didn't churn, and it tasted nothing like mint. Instead of regular mint, we used chocolate mint (which we planted specifically for making chocolate mint ice cream). The amount of work making it versus going to the store is relative to my decision to not make it again. I probably will not be making it again, because I am nuts about Dreyer's and Tillamook Choc. It made a difference to bring it close to what we are used to (store bought) as far as I am concerned. I followed the recipe to a tee, except I put a few drops of peppermint oiling it. It is a very weird color, no one can deny that. But only the amount of Mint leaves for one batch. Disgusting he garlic power made it taste all bad If you don't use that passcode before it expires then a new passcode is generated and the countdown begins again. If the account is a third-party OTP account (meaning you logged into another service like Gmail and added this device as an authenticator app), then you'll see a 30 second countdown indicator on the right. Tap the arrows to generate a new Duo passcode. If the account is a Duo native account (meaning you enrolled this device into Duo and activated the app for Duo Push), then the passcode shown is valid until used. This works anywhere, even in places where you don't have an internet connection or can't get cell service. Tap the down indicator to get a one-time passcode for login. Swipe down on the Duo Mobile banner notification received when your screen is unlocked to reveal additional actions. On devices that do not feature 3D Touch, swipe left on the lock screen Duo Mobile notification to reveal additional actions. Tap an action and supply your passcode or biometric verification (face or fingerprint) to complete the action. On Apple devices that support 3D Touch, performing a firm longpress on the Duo Mobile notification from the lock screen reveals the "Approve" or "Deny" actions. The actions presented to you wen you respond to the notification depend on your organization's Duo policy settings, such as whether or not you can approve the login request without PIN or biometric verification. You can respond to Duo Push requests from the iOS lock screen or banner notification starting with Duo Mobile version 3.8. If you're not able to scan your fingerprint using the TouchID sensor you can also approve the Duo authentication request using the device's passcode by tapping Cancel. If you're using a Touch ID capable iOS device you'll see a Touch ID prompt each time you authenticate via Duo Mobile (if required by your administrator). If you're not able approve the login request with Face ID you can tap Cancel and approve the Duo authentication request using the device's passcode.ĭuo Mobile 3.7 and later for iOS also supports Touch ID for Duo Push-based logins as an additional layer of security to verify user identity. If your first try isn't successful, tap Try Face ID Again to scan your face again. Scan your face in the same manner that you use to unlock your iPhone X to approve the Duo login request. The first time you receive a Duo Push request on your iPhone X that requires biometric verification, you'll be prompted to grant Face ID permission to the Duo Mobile app. If your Duo admin requires biometric verification when approving Duo requests you'll see the Face ID icon in the Duo Push request. You can approve Duo authentication requests with Face ID on your iPhone X with Duo Mobile 3.19 and later. You’ll be given the ability to report it as fraudulent, or you can tap It was a mistake to deny the request without reporting it. If you get a login request that you weren't expecting, press Deny to reject the request. You'll get a login request sent to your phone - just press Approve to authenticate. Duo Pushĭuo Push is the easiest and quickest way of authenticating. The "System Info" section shows the app version. To see which version of Duo Mobile is installed on your device, go to the iOS Settings menu, then scroll down and tap Duo Mobile. Support for older Duo Mobile versions on iOS 9.0 ended April 1, 2018. Supported Platforms: The current version of Duo Mobile supports iOS 10.0 and greater. You can also quickly generate login passcodes, even without an internet connection or cell service.įind the latest version of Duo Mobile in the App Store. The customer requests information about features, implementation, or configuration for Cisco’s hardware, software, or as a service product.The Duo Mobile application makes it easy to authenticate - just tap “Approve” on the login request sent to your iPhone. No impact on the customer’s business operations. Cisco hardware, software or as a service product is partially degraded. Minimal impact on the customer’s business operations. High, users may be unable to access applicationsĭuo Care customers: call Duo Support directly Cisco hardware, software or as a service product is degraded. Substantial impact on the customer’s business operation. High, outage prevents access to applications Cisco’s hardware, software or as a service product is down. Critical impact on the customer’s business operations. A Qualifying Purchase is defined as a purchase of 8 gallons or more of Synergy Supreme+ fuel with the Exxon Mobil Rewards+ program. §Exxon Mobil Rewards+ Premium Status (“Premium Status”) is achieved by making three (3) “Qualifying Purchases” in a calendar month. Concentration and availability of our proprietary additive package may vary based on factors beyond our control. Actual benefits are based on continuous use and may vary depending on vehicle type, driving style, and gasoline previously used. Wear reduction was measured by an industry standard lubricant test. ‡‡Based on Synergy Supreme+ gas compared to gasoline meeting minimum government standards. Concentration and availability of our proprietary additive package may vary based upon factors beyond our control. Actual benefits will vary based on factors such as vehicle type, driving style and gasoline previously used. §§Benefits are based on Synergy-branded gasoline compared to gasoline meeting minimum U.S. ‡Based on comparison of Synergy Supreme+™ premium gas to our regular gas in port fuel injected engines. Please note T-Chek will only authorize transactions at commercial truck fueling locations Actual benefits will vary depending on factors such as vehicle/engine type, driving style and diesel fuel previously used.Ĭommercial Diesel Fleet Cards include FleetPro, EFS, FleetOne, T-Chek. †Claims apply to Exxon and Mobil Synergy Diesel Efficient-branded fuel compared to diesel fuel without detergent additive. See full program details in the Albertsons Banner stores’ mobile apps or websites. Grocery Rewards may be redeemed on an offered item only if your Rewards balance equals or exceeds Rewards required for that item. Gas Reward savings are limited to 25 gallons for one vehicle per transaction - subject to rounding for Exxon Mobil in-store fuel transactions and/or transaction dollar limits on your payment card set by your financial institution. **Maximum Gas Reward at participating Exxon™ and Mobil™ stations is $1 per gallon of Exxon- and Mobil-branded fuel and up to $1 per gallon at Albertsons Companies Banner gas stations. *Based on comparison of Synergy Supreme+ gas compared to Synergy regular gas in port fuel injected engines. Walmart+ discount available at participating Exxon and Mobil stations. With that said, we are doing our best to provide useful information and obviously, directions to the nearest gasoline station.Find Gas Stations Near Me | Exxon and Mobil The website is not associated with any fuel company and cannot guarantee that you will find a gas station near you. In the United States, there are variety of petrol stations, some offers full service while others only provide limited services such as car wash, some are open all day long while others have fixed hours of operation, and might be closed on Sunday, also, in some filling stations, the gas is cheaper than in others. In a case that you are searching for a gas station open right now, this site also comes in handy, for instance, the open 24/7 category was created especially to inform you about the locations of gas-stations that are open now and late at night.įurthermore, in addition to gas stations open near me, we strive to share general information about all the major gas station companies, including the most relevant information, like how to find gas near me now, and other things from that nature. This site is useful not only because it shows maps of nearby gas stations, although this is the main reason, but also because it’s updated regularly with more information about fuel stations in the US, such as phone numbers and street addresses, to make it easier for you to locate a station in your area. This website offers a simple and easy-to-use fuel locator, after you’ve selected the category (such as ‘Diesel’ or ‘Open 24 hours’), or a particular gas company (such as Shell or BP) from the menu, you’ll be presented with maps that will show you exactly where are the gas stations close to you now. Are you searching for ‘ gas station near me‘? Would you like to find the closest gas station around you now? Use the map to locate gas stations near your current location or within a short driving distance.
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